90plus 纳米粒度仪应用案例-18

90plus纳米粒度仪应用案例
文献名:electrospinningandsolutionpropertiesofnafionandpoly(acrylicacid)
作者:hongchen,joshuad.snyder,andyossefa.elabd*
departmentofchemicalandbiologicalengineering,drexeluniversity,philadelphia,pennsylvania19104
摘要:inthisstudy,theelectrospinningperformanceandsolutionpropertiesofnafionanditsblendwithanotherpolyelectrolyte,poly(acrylicacid)(paa),wereinvestigated.attemptstoelectrospinpurenafionatvariouspolymerconcentrations(5−35wt%),solvents,neutralization,andelectrospinningconditionsresultedinelectrosprayingratherthanelectrospinning.however,apolymersolutionblend(5wt%)ofnafionandpaaresultedinbeadedfibersat8wt%paaandsmoothelectrospinningabove12%paa.fibersizesoftheblendincreasedfrom90to600nmwithincreasingpaacontent.dynamiclightscatteringonpurenafionsolutionsinvarioussolventsrevealslargeaggregates(i.e.,dispersion)ofvarioussizesduetopolymerbackboneandionicinteractions.thelackofsufficientpolymerchainentanglementevidencedbylowviscosityandaggregateformationinnafionsolutionsprohibitsfiberformationduringelectrospinning.theadditionofpaatonafionmodifiestheionicstrengthofthesolventresultinginsuppressedaggregateformation,increasedviscosity,andsubsequentlyenhancedpolymerchainentanglement.coincidentally,theonsetofsuppressedaggregateformationintheblendsolutioncoincideswiththeelectrospraying−electrospinningtransition(8%paa).inaddition,thermaltreatmentenhanceswaterstabilityoftheelectrospunblendfibers.

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90plus 纳米粒度仪应用案例-18
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